Download Applied Mechanics, Materials, Industry and Manufacturing by Helen Zhang and David Jin PDF

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By Helen Zhang and David Jin

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References: [1] Pan Dong-hui, Fu Guang-hui, Du Jia-feng. Metal alkoxide synthesis and application J. Chemistry. 11(1989) [2] Yang Yun-xia, Xu Zhi-zhen, Yuan Shuang-long, etc. The study of nano-Al2O3 with the light-emitting J. Journal of Rare Earth, 6:20(2002) [3] Shanghai Chemical research and technological achievements, Application technology. (2007). [4] Wilds A. 178 (1953) [5] Inorganic Chemistry (Volume 2), Beijing Normal University, China Central Normal University, Inorganic Chemistry Department of Nanjing Normal University M.

5 on different values of log[Ca]0 was drawn, so the slope of the line is(1-n). 4  P P0 (5) [Ca ] 3 (6) The concentration of the alcohol and isopropoxide could be calculated at different time. 5 of different starting concentration [Ca] 0 could be checked from the statistics of the calculation. 5 at different values of log[Ca]0 are shown in Table 1. The curve according to the statistics of Table 1 is shown in Fig. 3. 07335, so the order of the reaction n≈0. The reaction is no relationship with the concentration of alcohol, but the state of the surface of aluminum.

2. The reaction rate of aluminum (overdosed) in isopropanol was calculated. The rate of H2 generation was delegated as the reaction rate. The curve could divide into four stages: (1) Stage of surface acting, the time when the active layer formed was the induction period. (4) Stage of reaction rate rapidly descending, the content of aluminum isopropoxide approached to 100% meanwhile the content of alcohol to zero, reaction rate sharply descended from the highest value to zero. 2 Determination of the order of reaction and the reaction equation (a) When aluminum was overdosed, the concentration of the alcohol was zero after the reaction.

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